Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin† †Electronic supplementary information (ESI) available: General procedures, synthetic details, NMR spectra, EPR spectra, IR spectra, electronic absorption and emission spectra, voltammetric data, X-ray crystallographic data, computational details and optimised geometries. CCDC 1446511, 1446512 and 1507634. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc02912d Click here for additional data file. Click here for additional data file.

Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups† †Electronic supplementary information (ESI) available: Experimental details. Additional views of the molecular structures from X-ray diffraction. Cyclic voltammograms of 2 and 3. Plots of calculated lowest energy transitions versus UV-visible absorption spectra. Variable-temperature emission and excitation spectra. Copies of all NMR spectra. Cartesian coordinates of all optimised geometries. CCDC 1010408–1010412. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02410a Click here for additional data file. Click here for additional data file.

Institut für Anorganische Chemie, Julius Hubland, 97074 Würzburg, Germany. E-ma School of Medicine, Pharmacy and Health, Stockton-on-Tees, TS17 6BH, UK Department of Chemistry, University of Tor M5S 3H6, Canada Institut für Organische Chemie, JuliusHubland, 97074 Würzburg, Germany † Electronic supplementary information Additional views of the molecular stru voltammograms of 2 and 3. Plots of ca...

Gold(iii)–arene complexes by insertion of olefins into gold–aryl bonds† †Electronic supplementary information (ESI) available: Experimental details (syntheses, analytical data and copies of 1H, 13C and 31P NMR spectra), crystallographic data of 2 and computational details. CCDC 1526613 and 1538015. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00145b Click here for additional data file. Click here for additional data file.

Crystalline boron-linked tetraaminoethylene radical cations† †Electronic supplementary information (ESI) available: NMR spectra, crystallographic data, crystal structures, UV-vis spectra, cyclic voltammograms, EPR spectra, and theoretical calculation. CCDC 1548460–1548466. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03528d Click here for additional data file. Click here for additional data file.

A nitrogen-base catalyzed generation of organotin(ii) hydride from an organotin trihydride under reductive dihydrogen elimination† †Electronic supplementary information (ESI) available: Detailed information concerning the general synthetic procedures, NMR spectroscopy and crystallographic details. Detailed explanations on the kinetic measurements and selected 1D NMR spectra as well as details on the computational considerations. CCDC 1061347–1061349. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01561h Click here for additional data file. Click here for additional data file.

Institut für Anorganische Chemie, Auf Germany. E-mail: lars.wesemann@uni-tueb School of Chemistry, Monash University, PO Institut für Organische Chemie, Auf der Mo † Electronic supplementary information concerning the general synthetic p crystallographic details. Detailed explanat selected 1D NMR spectra as well considerations. CCDC 1061347–1061349. CIF or other electronic format see DOI: 10 Ci...

Synthesis of a novel polycyclic ring scaffold with antimitotic properties via a selective domino Heck–Suzuki reaction† †Electronic supplementary information (ESI) available: Full experimental details, 1H and 13C NMR spectra and X-ray crystallographic data for compound 4d. CCDC 936207. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02547d Click here for additional data file. Click here for additional data file.